Surface Embedded Nanotubes


Assembly of carbon nanotubes from as-grown randomly tangled states into well-ordered and uniform manner has attracted considerable attentions from researchers and engineers worldwide due to specific properties of the carbon nanotubes and its importance for chemical, biomedical and engineering applications. Carbon nanotubes show their superior properties for binding biomolecules with a three-dimensional nano-architecture and highly dense functional groups on the surfaces. For sensors, biochips, and many other applications, the well-ordered and functionalized carbon nanotubes are greatly desirable. However, the creation of properly oriented nanotubes remains a big challenge due to their fragility and that technology has not been broadly commercialized.

MicroDysis has developed a straightforward and effective technique to entrap SWNTs onto a polymer surface, such as elastomer or silicone rubber, and plastics. Figure below shows Atomic Force Microscope (AFM) images (in Tapping-Mode) of a spot of the carboxylized nanotubes on a polymer surface.


Atomic Force Microscopy(AFM) images(three-dimensional surface profile) of (a) a blank polymer surface and (b) a polymer surface entrapped carboxylized single-walled carbon nanotube.


AMF image clearly shows that well-controlled upright nanotube architectures on the polymer surface. The average height of the entrapped CNTs on the surface is around 30 nm. The nanotubular features of the nanotubes on the surface significantly enhance sensing surface area about 10,000 times more than a blank surface. With the functionalized surface feature (-COOH groups) on the nanotubes, SENT will be found wide applications in binding sensing molecules for DNA and protein analysis, and chemical compound and ion detection.

Advantages:
• Vertical assembled single-walled carbon nanotubes on polymer matrix.
• Surface area increased about 10,000 times.
• Highly dense-COOH groups for chemically binding sensing molecules.
• Versatile sensing platform.

                  Sep 07, 2010

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